Fast Oxidation Reaction of Nitrite by Dissolved Oxygen in the Freezing Process in the Tropospheric Aqueous Phase     

Norimichi Takenaka  Tohru Daimon  Akihiro Ueda  Keiichi Sato  Masaru Kitano  Hiroshi Bandow  Yasuaki Maeda 《Journal of Atmospheric Chemistry》1998,29(2):135-150

Nitrite oxidation in the tropospheric aqueous phase by freezing was evaluated by freezing a field sample. Nitrite oxidation by dissolved oxygen in the freezing process is much faster than by other oxidation processes, such as reactions with ozone, hydrogen peroxide or dissolved oxygen in an aqueous solution at pHs 3 to –6. At pH 4.5 and 25°C, the lifetime of nitrite in the aqueous phase is ca. 1 hr in oxidation by ozone (6×10^-10 mol dm^-3), ca. 10 hr in oxidation by H₂O₂ (2×10^-4 mol dm^-3), and 7.5 hr (Fischer and Warneck, 1996) in photodissociation at midday in summer. Under the same conditions at a temperature below 0°C, the lifetime of nitrite in the freezing process is estimated as ca. 2 sec when the droplets are frozen within a second. The reaction by freezing is affected by the presence of salts, such as NaCl or KCl, or orgnaic compounds, such as methanol or acetone. The results of freezing a field rain or fog sample showed that nitrite oxidation proceeds below pH 6, and the conversion ratio of nitrate from nitrite increases with decreasing pH. The oxidation of nitrite by freezing was also observed in freezing fog particles generated by an ultrasonic humidifier. The ratios of the concentrations of ions in the winter sample to those in the summer sample (or those in the fog sample) were almost the same values. However, the concentration of nitrite in the winter sample was lower than that estimated by the ratios of other ions. From the present study, it seems that the freezing process plays an important role in the nitrite sink process in the tropospheric aqueous phase.  相似文献   

Frequency-dependent Attenuation of High-frequency P and S Waves in the Upper Crust in Western Nagano, Japan     

K. Yoshimoto  H. Sato  Y. Iio  H. Ito  T. Ohminato  M Ohtake 《Pure and Applied Geophysics》1998,153(2-4):489-502

—Borehole seismograms from local earthquakes in the aftershock region of the 1984 western Nagano Prefecture, Japan earthquake were analyzed to measure the frequency-dependent characteristics of P- and S-wave attenuation in the upper crust. The records from a three-component velocity seismometer at the depth of 145m exhibit high S/N-ratio in a wide frequency range up to 100 Hz. Extended coda normalization methods were applied to bandpass-filtered seismograms of frequencies from 25 to 102 Hz. For the attenuation of high-frequency P and S waves, our measurements show Q _P ^-1? 0.052?^-0.66 and Q _S ^-1? 0.0034?^-0.12 respectively. The frequency dependence of the quality factor of S waves is very weak as compared with that of P waves. The ratio of Q _P ^-1/Q _S ^-1 is larger than unity in the entire analyzed frequency range.  相似文献   

A new technique for measuring diffusion coefficients of cations and anions in ionic crystals     

Hiroki Sato  Yoshiaki Ida 《Physics of the Earth and Planetary Interiors》1981,25(4):396-405

A new technique has been developed for measuring the diffusion coefficient in ionic crystals. Based on Einstein's formula expressing the relation between diffusion coefficient and electric mobility, the electrical impedance of a diatomic ionic crystal is derived theoretically as a function of frequency of the applied electric field. In this method, the diffusion coefficients of both cations and anions are determined simultaneously by fitting the measured impedance to the theoretical relation. This method was applied to NaCl single crystals in the temperature range 370–780°C. The impedance was determined over the frequency range 0.01 Hz to 1 kHz, at constant temperature. The diffusion coefficients thus obtained for NaCl agree reasonably well with previous data by means of a radioactive isotope technique. The activation energies for Na⁺ and Cl^? obtained are 1.97±0.03 eV and 2.08±0.06 eV, respectively, in the intrinsic region, and 0.92±0.02 eV and 1.06±0.02 eV in the extrinsic region. It was discovered that there are diffusion blocks of approximately 2 μm width, which obstruct free migration of ions in a single crystal.  相似文献   

Mixed layer depth climatology of the North Pacific based on Argo observations   总被引：2，自引：1，他引：1  

Yuko Ohno  Naoto Iwasaka  Fumiaki Kobashi  Yoshiko Sato 《Journal of Oceanography》2009,65(1):1-16

A monthly mean climatology of the mixed layer depth (MLD) in the North Pacific has been produced by using Argo observations. The optimum method and parameter for evaluating the MLD from the Argo data are statistically determined. The MLD and its properties from each density profile were calculated with the method and parameter. The monthly mean climatology of the MLD is computed on a 2° × 2° grid with more than 30 profiles for each grid. Two bands of deep mixed layer with more than 200 m depth are found to the north and south of the Kuroshio Extension in the winter climatology, which cannot be reproduced in some previous climatologies. Early shoaling of the winter mixed layer between 20–30°N, which has been pointed out by previous studies, is also well recognized. A notable feature suggested by our climatology is that the deepest mixed layer tends to occur about one month before the mixed layer density peaks in the middle latitudes, especially in the western region, while they tend to coincide with each other in higher latitudes.  相似文献   

Short-term temperature and salinity variations in the Tsushima Strait in 2004: Behavior of the surface low-salinity water in the strait     

Kosuke Mori  Takeshi Matsuno  Tomoharu Senjyu  Naoki Hirose  In-Seong Han 《Journal of Oceanography》2009,65(3):301-310

Temporal variations in temperature and salinity observed in 2004 were investigated on a short time scale in the Tsushima Strait. The data were obtained by long-term in situ measurements at Mitsushima and Futaoi Island using an instrument equipped with a piston-type wiper to avoid biofouling. In addition, the temperature and salinity values of the surface layer obtained by a commercial ferryboat between Hakata and Busan were used to investigate their spatiotemporal variations. Temperature and salinity variations with a time scale of several days had a negative correlation in the summer. This evidence suggests that a warm and less saline water mass, which is considered to be mainly the Changjiang Diluted Water (CDW), flowed intermittently through the Tsushima Strait in summer. In late July 2004, a large low-salinity water mass was detected in the Tsushima Strait. At that time, the freshwater transport through the Tsushima Strait transiently reached about 12 × 10⁴ m³s⁻¹, which is estimated from observed acoustic Doppler current profiler (ADCP) data along a ferryboat line and inferred salinity profiles. This estimated value is more than double the maximum of the climatological monthly mean of the Changjiang discharge. Furthermore, salinity and surface current data obtained by high frequency ocean radar (HF radar) indicate that water properties at Mitsushima may occasionally represent part of the water flowing through the western channel via a countercurrent, although Mitsushima is geographically located in the eastern channel.  相似文献   

Local effects on tidal strain measurements at Esashi, Japan     

T. Sato  J. C. Harrison 《Geophysical Journal International》1990,102(3):513-526

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Cluster analysis on the bulk elemental compositions of Antarctic stony meteorites          下载免费PDF全文

Hideaki Miyamoto  Takafumi Niihara  Takeshi Kuritani  Peng K. Hong  James M. Dohm  Seiji Sugita 《Meteoritics & planetary science》2016,51(5):906-919

Remote sensing observations by recent successful missions to small bodies have revealed the difficulty in classifying the materials which cover their surfaces into a conventional classification of meteorites. Although reflectance spectroscopy is a powerful tool for this purpose, it is influenced by many factors, such as space weathering, lighting conditions, and surface physical conditions (e.g., particle size and style of mixing). Thus, complementary information, such as elemental compositions, which can be obtained by X‐ray fluorescence (XRF) and gamma‐ray spectrometers (GRS), have been considered very important. However, classifying planetary materials solely based on elemental compositions has not been investigated extensively. In this study, we perform principal component and cluster analyses on 12 major and minor elements of the bulk compositions of 500 meteorites reported in the National Institute of Polar Research (NIPR), Japan database. Our unique approach, which includes using hierarchical cluster analysis, indicates that meteorites can be classified into about 10 groups purely by their bulk elemental compositions. We suggest that Si, Fe, Mg, Ca, and Na are the optimal set of elements, as this set has been used successfully to classify meteorites of the NIPR database with more than 94% accuracy. Principal components analysis indicates that elemental compositions of meteorites form eight clusters in the three‐dimensional space of the components. The three major principal components (PC1, PC2, and PC3) are interpreted as (1) degree of differentiations of the source body (i.e., primitive versus differentiated), (2) degree of thermal effects, and (3) degree of chemical fractionation, respectively.  相似文献   

A multi-proxy reconstruction of spatial and temporal variations in Asian summer temperatures over the last millennium   总被引：1，自引：0，他引：1  

Feng?Shi  Quansheng?GeEmail author  Bao?Yang  Jianping?Li  Fengmei?Yang  Fredrik?Charpentier?Ljungqvist  Olga?Solomina  Takeshi?Nakatsuka  Ninglian?Wang  Sen?Zhao  Chenxi?Xu  Keyan?Fang  Masaki?Sano  Guoqiang?Chu  Zexin?Fan  Narayan?P.?Gaire  Muhammad?Usama?Zafar 《Climatic change》2015,131(4):663-676

To investigate climate variability in Asia during the last millennium, the spatial and temporal evolution of summer (June–July–August; JJA) temperature in eastern and south-central Asia is reconstructed using multi-proxy records and the regularized expectation maximization (RegEM) algorithm with truncated total least squares (TTLS), under a point-by-point regression (PPR) framework. The temperature index reconstructions show that the late 20th century was the warmest period in Asia over the past millennium. The temperature field reconstructions illustrate that temperatures in central, eastern, and southern China during the 11th and 13th centuries, and in western Asia during the 12th century, were significantly higher than those in other regions, and comparable to levels in the 20th century. Except for the most recent warming, all identified warm events showed distinct regional expressions and none were uniform over the entire reconstruction area. The main finding of the study is that spatial temperature patterns have, on centennial time-scales, varied greatly over the last millennium. Moreover, seven climate model simulations, from the Coupled Model Intercomparison Project Phase 5 (CMIP5), over the same region of Asia, are all consistent with the temperature index reconstruction at the 99 % confidence level. Only spatial temperature patterns extracted as the first empirical orthogonal function (EOF) from the GISS-E2-R and MPI-ESM-P model simulations are significant and consistent with the temperature field reconstruction over the past millennium in Asia at the 90 % confidence level. This indicates that both the reconstruction and the simulations depict the temporal climate variability well over the past millennium. However, the spatial simulation or reconstruction capability of climate variability over the past millennium could be still limited. For reconstruction, some grid points do not pass validation tests and reveal the need for more proxies with high temporal resolution, accurate dating, and sensitive temperature signals, especially in central Asia and before AD 1400.  相似文献   

Long-term evolution of the aerosol debris cloud produced by the 2009 impact on Jupiter     

A. Sánchez-Lavega  G.S. Orton  R. Hueso  L.N. Fletcher  E. García-Melendo  I. de Pater  H.B. Hammel  A. Simon-Miller  F. Marchis  O. Mousis  J. García-Rojas  M. Cecconi  K. Noll  S. Pedraz  P. Kalas  W. Golisch  P. Sears  V. Reddy  R. Binzel  W. Grundy  J. Emery  A. Rivkin  C. Thomas  D. Trilling  K. Bjorkman  A.J. Burgasser  H. Campins  T.M. Sato  Y. Kasaba  J. Ziffer  R. Mirzoyan  H. Bouy 《Icarus》2011,214(2):462-476

We present a study of the long-term evolution of the cloud of aerosols produced in the atmosphere of Jupiter by the impact of an object on 19 July 2009 (Sánchez-Lavega, A. et al. [2010]. Astrophys. J. 715, L155-L159). The work is based on images obtained during 5 months from the impact to 31 December 2009 taken in visible continuum wavelengths and from 20 July 2009 to 28 May 2010 taken in near-infrared deep hydrogen-methane absorption bands at 2.1-2.3 μm. The impact cloud expanded zonally from ∼5000 km (July 19) to 225,000 km (29 October, about 180° in longitude), remaining meridionally localized within a latitude band from 53.5°S to 61.5°S planetographic latitude. During the first two months after its formation the site showed heterogeneous structure with 500-1000 km sized embedded spots. Later the reflectivity of the debris field became more homogeneous due to clump mergers. The cloud was mainly dispersed in longitude by the dominant zonal winds and their meridional shear, during the initial stages, localized motions may have been induced by thermal perturbation caused by the impact’s energy deposition. The tracking of individual spots within the impact cloud shows that the westward jet at 56.5°S latitude increases its eastward velocity with altitude above the tropopause by 5-10 m s⁻¹. The corresponding vertical wind shear is low, about 1 m s⁻¹ per scale height in agreement with previous thermal wind estimations. We found evidence for discrete localized meridional motions with speeds of 1-2 m s⁻¹. Two numerical models are used to simulate the observed cloud dispersion. One is a pure advection of the aerosols by the winds and their shears. The other uses the EPIC code, a nonlinear calculation of the evolution of the potential vorticity field generated by a heat pulse that simulates the impact. Both models reproduce the observed global structure of the cloud and the dominant zonal dispersion of the aerosols, but not the details of the cloud morphology. The reflectivity of the impact cloud decreased exponentially with a characteristic timescale of 15 days; we can explain this behavior with a radiative transfer model of the cloud optical depth coupled to an advection model of the cloud dispersion by the wind shears. The expected sedimentation time in the stratosphere (altitude levels 5-100 mbar) for the small aerosol particles forming the cloud is 45-200 days, thus aerosols were removed vertically over the long term following their zonal dispersion. No evidence of the cloud was detected 10 months after the impact.  相似文献   

Japanese early-warning for debris flows and slope failures using rainfall indices with Radial Basis Function Network   总被引：3，自引：1，他引：2  

Nobutomo Osanai  Takeshi Shimizu  Kazumasa Kuramoto  Shinichi Kojima  Tomoyuki Noro 《Landslides》2010,7(3):325-338

Early-warning systems for natural disasters are important tools for disaster risk reduction and for achieving sustainable development and livelihoods. In 2005, the Japanese government initiated a new nationwide early-warning system for landslides disasters. The main methodology of the system is to set a criterion for occurrences of debris flows and slope failures based on several rainfall indices (60-min cumulative rainfall and soil–water index) in each 5-km grid mesh covering all of Japan. Because many of the records of mass movements are lacking in scientific precision on timing and location, the system applies Radial Basis Function Network methods to set the criterion based primarily on rainfall data recorded as not triggering disasters. Since the end of March 2007, under torrential rainfall conditions, early-warning information has been disseminated as part of weather news using TV, radio, and the Internet. Because of the increasing worldwide recognition of the importance of early-warning systems for natural disaster reduction, the aim of this article is to introduce the new Japanese early-warning system to the international landslide community. In this article, the method, the system, and the result of its application to landslide disasters in 2009 are presented.  相似文献